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Openai/6946f4fa-e8bc-800b-b77e-c62f6390a97c
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=== ## === 主題:等電子比較|VSEPR|混成|分子形狀|鍵角|鍵長 ==== ### ==== EN Which ion is larger in each of the following pairs? 中 下列每一組中,哪一個離子的半徑較大? ===== - 等電子系列: → 核電荷越大,半徑越小 ===== * 同一元素: → 電荷越正,半徑越小 ===== 逐組比較,選擇: ===== * 電荷較小者 * 或核電荷較小者 ===== ✅ d ===== ==== ### ==== EN Select the element or compound that best fits each description: (i) most metallic (ii) most covalent (iii) highest electronegativity 中 選出最符合下列性質者: (i) 金屬性最強 (ii) 共價性最強 (iii) 電負度最高 ===== - 金屬性:左下角最大 ===== * 共價性:非金屬與非金屬 * 電負度:右上角(不含稀有氣體) ===== - (i) Ba:鹼土金屬、活潑 ===== * (ii) N₂O:非金屬間鍵結 * (iii) O:電負度高 ===== ✅ e. Ba, N₂O, O ===== ==== ### ==== EN How many electron pairs surround the central atom in XeF₂, and what is its molecular geometry? 中 XeF₂ 中心原子周圍有幾對電子?其分子形狀為何? ===== - Xe:8 價電子 ===== * XeF₂: - 2 鍵對 - 3 孤對 → 共 5 電子對 電子幾何:三角雙錐 孤對佔赤道 → 分子形狀線形 ===== ✅ e. 6 electron pairs, linear ===== (⚠️ 含鍵對+孤對) ==== ### ==== EN Which molecule has a square planar geometry? 中 哪一個分子具有'''正方平面(square planar)'''結構? ===== - AX₄E₂ → square planar ===== ===== - XeF₄: - 4 鍵 + 2 孤對 - 孤對位於軸向 - 鍵在同一平面 ===== ===== ✅ d. XeF₄ ===== ==== ### ==== EN What is the molecular geometry of XeF₅⁺? 中 XeF₅⁺ 的分子形狀為何? ===== - Xe:8 電子 − 1(正電) = 7 ===== * 5 鍵 + 1 孤對 → 6 電子域(八面體) 分子形狀:square pyramidal ===== ✅ b. square pyramidal ===== ==== ### ==== EN What is the approximate Cl–Kr–Cl bond angle in KrCl₄? 中 KrCl₄ 中 Cl–Kr–Cl 的鍵角約為多少? ===== - KrCl₄: - 4 鍵 + 2 孤對 - square planar ===== * 鄰鍵角:90° ===== ✅ a. 90° ===== ==== ### ==== EN Which molecule has the largest bond angle? 中 下列哪一個分子具有最大的鍵角? ===== - sp(線形) → 180° ===== * sp² → 120° * sp³ → ~109.5° ===== - HCN: - C 為 sp 混成 - 線形結構 → 鍵角 180° ===== ===== ✅ c. HCN ===== ==== ### ==== EN Which species has the greater N–O bond length, NO₂⁻ or NO₃⁻? 中 NO₂⁻ 與 NO₃⁻ 中,哪一個的 N–O 鍵較長? ===== : ===== ===== - NO₂⁻:平均鍵階 = 1.5 ===== * NO₃⁻:平均鍵階 = 4/3 ≈ 1.33 → 鍵階較小者鍵較長 ===== ✅ b. NO₃⁻ ===== ==== ### ==== EN What is the molecular geometry of NI₃? 中 NI₃ 的分子形狀為何? ===== - N:3 鍵 + 1 孤對 ===== * 電子幾何:四面體 * 分子形狀:三角錐 ===== ✅ a. pyramidal ===== ==== ### ==== EN What is the approximate bond angle in H₂Se? 中 H₂Se 的 H–Se–H 鍵角約為多少? ===== - 16 族氫化物: - H₂O:104.5° - H₂S:~92° - H₂Se:~90° ===== ===== ✅ e. 90° =====
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