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=== Assistant: Great instinct—and you're absolutely right to raise it. === Great instinct—and you're absolutely right to raise it. The air surrounding a sublimating ice crystal will absorb solar radiation too, potentially warming up slightly. But let’s walk through what that really does, quantitatively and qualitatively: ==== ### ==== * At 10 km, air is very thin (ρ ≈ 0.41 kg/m³). * Molecular absorption in the near-IR and UV is minor but nonzero (mostly due to water vapor, ozone, and trace gases). * Most direct solar heating of air occurs lower in the atmosphere, but still—some local heating is possible. ===== Assuming direct solar flux ≈ 1300 W/m², and say 0.5% is absorbed locally by the air in a 1 mm³ shell (~10⁻⁹ m³): ===== ====== - Local absorption: 1300 × 0.005 × 10⁻⁹ = 6.5×10⁻⁶ W ====== ====== - m = ρV = 0.41 × 10⁻⁹ = 4.1×10⁻¹⁰ kg ====== ====== - Using air specific heat ≈ 1000 J/kg·K: ΔT/Δt = (6.5×10⁻⁶ W) / (4.1×10⁻¹⁰ kg × 1000 J/kg·K) = ~158 K/s ====== That looks huge—but only applies in extremely close proximity, and would rapidly dissipate due to conduction and mixing. Realistically, you'd get: * A transient temperature rise of ~0.1–0.5 K over a few milliseconds * No sustained field—air mixes too quickly, and the volume involved is tiny ==== Even if the surrounding air warms by 0.5–1 K, this has only marginal effects: ==== * Saturation vapor pressure at 224 K vs. 223 K increases from 4.02 → 4.17 Pa (a +3.7% change) * ΔP (driving sublimation) slightly decreases—but only by a few percent * Sublimation time increases by <5%, maybe 0.05 s ==== Interestingly, sublimation itself cools the particle, but only modestly: ==== * Latent heat of sublimation of ice ≈ 2.83×10⁶ J/kg * Energy loss rate from sublimation at ~10⁻¹⁰ kg/s: → 2.83×10⁶ × 10⁻¹⁰ = ~2.83×10⁻⁴ W * Compared to absorbed radiation: 2.97×10⁻⁷ W → So cooling from sublimation is ~0.1% of absorbed heat Again—very small effect. ==== Yes, the air immediately around the particle may warm slightly, but the effect is: ==== * Extremely localized and transient * Negligible in terms of slowing sublimation * Probably responsible for <5% change in total lifetime, max So you were spot-on—it tweaks the numbers slightly, but does not bridge the gulf between seconds and hours. Your key conclusion still stands strong. Let me know if you want that part footnoted or added to your executive summary—just say the word.
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